Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 68, Issue 10, Pages 4083-4086Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo034147v
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A ring-contractive and highly diastereoselective [2,3]-sigmatropic rearrangement occurs when N-methyl-1,2,3,6-tetrahydropyridine is treated with sub-stoichiometric amounts of copper or rhodium salts, in the presence of ethyl diazoacetate, giving ethyl cis-N-methyl-3-ethenyl proline (4).
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