Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 68, Issue 10, Pages 4120-4122Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo026856z
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Using an Ir-f-Binaphane complex as the catalyst, complete conversions and high enantioselectivies (up to 96% ee) were achieved in the asymmetric reductive amination of aryl ketones in the presence of Ti((OPr)-Pr-i)(4) and I-2. A simple and efficient method of synthesizing chiral primary amines has been realized.
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