4.4 Article

Allylic and benzylic oxidation using cobalt(II) alkyl phosphonate modified silica

Journal

TETRAHEDRON LETTERS
Volume 44, Issue 22, Pages 4283-4286

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(03)00833-5

Keywords

benzylic; oxidation; steroids; cobalt; phosphonate; silica; immobilised reagents

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The allylic and benzylic oxidation of a range of substrates proceeds in good yield using catalytic quantities of cobalt(11) alkyl phosphonate modified silica and tert-butyl hydroperoxide. (C) 2003 Elsevier Science Ltd. All rights reserved.

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