Journal
ORGANIC LETTERS
Volume 5, Issue 11, Pages 1955-1958Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol034549p
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[GRAPHIC] The first class of zipper-shaped artificial duplexes, which are driven by multiple donor-acceptor interactions between electron-rich 1,5-dioxynaphthalene or 1,4-dioxybenzene and electron-deficient pyromellitic dimide units, have been studied in organic media by H-1 NMR, UV-vis, and vapor pressure osmometry. H-1 NMR binding investigations reveal substantial cooperativity of the donor-acceptor interaction in the duplexes.
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