Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 150, Issue 6, Pages J23-J31Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.1573203
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Conductivity and dielectric relaxation are measured on several uncycled Ni(OH)(2) powders whose composition and degree of crystallization differ. The role played by water molecules intercalated in the a motifs of the interstratified structure is pointed out. Further, it is shown that coprecipitated dopants such as Co(II) and Zn(II) lower conductivity. Finally, a schematic model based on protonic conduction is proposed to account for the electrical and dielectrical properties of these solids. (C) 2003 The Electrochemical Society.
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