4.7 Article

Evolution of FCC/BCC interface and its effect on the strengthening of severe drawn Cu-3 wt.% Cr

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 640, Issue -, Pages 45-50

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2015.03.226

Keywords

Metals and alloys; Mechanical properties; Precipitation; Grain boundaries; Crystal structure; Transmission electron microscopy

Funding

  1. National Natural Science Foundation of China [11202183]
  2. National High Technology Research and Development Program (863) of China [2011AA11A101]
  3. State Key Laboratory for Strength and Vibration of Mechanical Structures Program of Xi'an Jiaotong University [SV2014-KF-13]

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Metal composites have attracted great interest for the combination of high strength and high electrical conductivity. We take the Cu-3 wt.% Cr composite as a model system to reveal the structure-property relations in a large range of drawing strains (eta), and propose the strengthening mechanism during cold drawing. At small and moderate drawing strains, the incoherent and semi-coherent interfaces are effective barriers for dislocation motion and pile-up. The mechanical behaviors are described well by the Hall-Petch relation. The work hardening at eta < 4.5 is the direct consequence of the grain refinement and the increasing density of phase boundaries, which can be well modelled by a linear rule of mixture. Deviation is observed at eta > 4.5, when the strength gradually reaches a plateau. Microstructural analysis reveals that further refinement can hardly occur at high drawing strains due to the dynamic recovery process. Another characteristic of the turning point is the structural homogenization, i.e. the mechanical alloy induced inter-mixing and the full coherency. The transition of the interface coherency is clearly identified by both electron diffraction and high resolution transmission electron microscopy. The structural homogenization at the interface may alleviate the interfacial blockage to the dislocation slipping, indicating the existence of an interfacial strength limit. The linear rule of mixture is modified to account for this effect at eta > 4.5. The complete mechanical behavior of the Cu-3 wt.% Cr composite is captured by a piece-wise function. (C) 2015 Elsevier B.V. All rights reserved.

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