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Hydrophosphorylation of terminal alkynes catalyzed by palladium

Journal

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 39, Issue 6, Pages 797-806

Publisher

MAIK NAUKA/INTERPERIODICA
DOI: 10.1023/B:RUJO.0000003155.15312.f4

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A series of new 1-aryl-, 1-heteroaryl-, and 1-alkylethenylphosphonates was prepared by hydrophosphorylation of terminal acetylenes catalyzed by palladium. A stable in air complex Pd-2(dba)(3) (.) CHCl3 was applied as catalyst. The reaction mechanism is discussed.

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