Fabrication and characterization of p-type ZnO films by pyrolysis of zinc-acetate-ammonia solution

P-type zinc oxide films were prepared on glass substrates by pyrolysis of ultrasonically nebulized zinc-acetate-ammonia solution. UV-visible absorption spectra, X-ray diffraction, and Hall effect measurements were carried out. Results show that zinc oxide films prepared by this method are preferentially oriented with the c-axis perpendicular to the substrate surface. The results of Hall effect measurements show that p-type conducting ZnO films with hole concentrations as high as 2.5 x 10(17)cm(-3) were obtained by this method. (C) 2003 Elsevier Science B.V. All rights reserved.