Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2003, Issue 11, Pages 2128-2131Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200300006
Keywords
natural products; total synthesis; atropisomerism; antitumor agents; antiviral agents
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The total synthesis of naturally occurring pedunculagin (1) was achieved by the twofold intramolecular double esterification of enantiomerically pure (S)-hexabenzyloxydiphenic acid (4) with the D-glucose-derived sugar 2 as the key step. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
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