4.1 Article

Enthalpies of solution of organic solutes in the ionic liquid 1-methyl-3-ethyl-imidazolium bis-(trifluoromethyl-sulfonyl) amide

Journal

JOURNAL OF SOLUTION CHEMISTRY
Volume 32, Issue 6, Pages 519-526

Publisher

KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1025361832209

Keywords

enthalpy of solution; ionic liquid; titration calorimetry

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Enthalpies of solution of six organic solutes in the ionic liquid 1-methyl-3-ethyl-imidazolium bis-(trifluoromethyl-sulfonyl) amide have been measured at 25degreesC at low concentrations using titration calorimetry. Results at infinite dilution are compared with data obtained indirectly from activity coefficients at infinite dilution. Thermodynamic consistency has been confirmed within the experimental error of both methods.

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