Uniformity in a thin-zone multi-pulse TAP experiment: numerical analysis

The thin-zone TAP reactor (TZTR) model of a multi-pulse experiment is computationally validated based on a more general three-zone reactor model. The analysis is focused on the uniformity of gaseous and surface concentrations in the catalyst zone, which is a key property of TZTR model. It is shown that if the TZTR model is valid for the first pulse in a multi-pulse experiment then it is valid for all subsequent pulses. For a typical reactor packing (the ratio of the thin-zone thickness to the length of reactor is 1/30) and with the first pulse conversion up to 97%, the gaseous and surface concentration profiles can be considered uniform and characterized by their spatial average values only. The reaction rate in the catalyst zone may also be characterized by its spatial average value and directly related to the spatial average gaseous and surface concentrations, in the same way as an elementary rate is related to concentrations. As a result of these unique characteristics, the TZTR may be considered a perfectly-mixed reactor even at high conversion. (C) 2003 Elsevier Science Ltd. All rights reserved.