4.4 Article

DABCO- and DBU-accelerated green chemistry for N-, O-, and S-benzylation with dibenzyl carbonate

Journal

TETRAHEDRON LETTERS
Volume 44, Issue 24, Pages 4563-4565

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(03)00992-4

Keywords

nucleophilic catalyst; DABCO; DBU; benzylation; dibenzyl carbonate; green chemistry

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An environmentally friendly process for the benzylation of nitrogen, oxygen, or sulfur atoms with dibenzyl carbonate has been developed. Catalytic amounts of DABCO or DBU can accelerate this 'green' alkylation. (C) 2003 Elsevier Science Ltd. All rights reserved.

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