4.4 Article Proceedings Paper

Precise determination of the Soret, thermal diffusion and mass diffusion coefficients of binary mixtures of dodecane, isobutylbenzene and 1,2,3,4-tetrahydronaphthalene by a holographic grating technique

Journal

PHILOSOPHICAL MAGAZINE
Volume 83, Issue 17-18, Pages 1973-1987

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/0141861031000108213

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Within the framework of an international benchmark test, the Soret coefficient S-T, thermal diffusion coefficient D-T and mutual mass diffusion coefficient D of the three binary mixtures of dodecane, isobutylbenzene and 1,2,3,4-tetrahydronaphthalene with a concentration of 50wt% of each component at a temperature of 25degreesC have been measured with a holographic grating technique. For the analysis of the experimental data a new numerical correction algorithm based on linear response theory has been employed. The corrections applied are on the order of 1% for ST and 5 % for D. The coefficients ST, D and DT are determined with relative errors of a few per cent.

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