Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 118, Issue 23, Pages 10729-10734Publisher
AIP Publishing
DOI: 10.1063/1.1574313
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A new quadrilayer surface phase, and its transition to bilayer and liquid surface phases, are observed by x-ray and surface tension measurements in the surface-frozen layer of a binary mixture of similar to20%C26OH:80%C18OH alcohols. The surface phase diagram is rationalized qualitatively based on the free energy landscape. A quantitative elucidation of the molecular-level origin of these effects is not currently available. (C) 2003 American Institute of Physics.
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