Journal
ORGANIC LETTERS
Volume 5, Issue 13, Pages 2303-2306Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol034641l
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[GRAPHICS] A highly enantioselective addition of silyl enol ethers derived from simple methyl ketones is described. The catalyst system of silicon tetrachloride activated by a chiral bisphosphoramide (R,R)-7 effectively promotes the addition of a variety of unsubstituted silyl enol ethers to aromatic, olefinic, and heteroaromatic aldehydes in excellent yield.
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