Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 68, Issue 13, Pages 5211-5216Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo034331g
Keywords
-
Categories
Ask authors/readers for more resources
Several inorganic esters have been evaluated as phosphoryl transfer catalysts. Of these, Ti(t-BuO)(4) was found to be the most effective catalyst giving excellent yields of the desired phosphate esters. The loading of the catalyst could be reduced to a little as 5 mol % for a majority of substrates with no loss in the yield of product. This methodology is significantly more versatile than using TiCl4 and is suitable for the phosphorylation of more complex carbohydrates and molecules of biological interest.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available