Journal
INORGANIC CHEMISTRY
Volume 42, Issue 13, Pages 3981-3987Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic0260567
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A series of (VO)-O-IV bis chelated complexes of alpha-hydroxycarboxylic acids with a 2(COO-, O-) coordination set was analyzed by electronic absorption and EPR spectroscopy in aqueous solution. All the complexes exhibit a square-pyramidal geometry distorted toward trigonal bipyramid. The influence of the distortion of the geometry, as deduced from the steric hindrance produced by the substituents at the alpha-carbon atom of the ligands, on the spectroscopic parameters has been studied. The observed trends were related to the electronic structure of the metal ion in the distorted geometry.
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