4.6 Article

Electrochemical properties of new n-type π-conjugated polybipyridines and polybiphenylenes with various bridging units

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 5, Issue 7, Pages 566-570

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/S1388-2481(03)00119-X

Keywords

electrochemical reduction; pi-conjugated polymer; polybipyridine; polybiphenylene; bridging group; n-Type doping

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New electrochemically active pi-conjugated polymers were prepared. They had polybipyridine or polybiphenylene type structure with an -N=N-, -O-, or -NHCONH- bridging group between the two aromatic units, and underwent more facile electrochemical reduction (or n-type doping) than the mother pi-conjugated polymers without the bridging group. (C) 2003 Elsevier Science B.V. All rights reserved.

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