Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 618, Issue -, Pages 67-72Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2014.07.203
Keywords
ZnO/CdS nanocomposites; Low-temperature solid-state synthesis; Optical properties; Formation mechanism
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Funding
- Nanjing University of Aeronautics and Astronautics [NS2013060]
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A simple low-temperature solid-state reaction in the presence of the surfactant PEG400 was developed to obtain ZnO/CdS nanocomposites. The effects of synthesis temperature and reaction time on crystal structure and optical properties of the nanocomposites were investigated by several technologies. X-ray diffraction (XRD) and high resolution transmission electron microscope (HRTEM) characterizations showed that the products consisted of the nanoparticles, and the grain growth kinetics of the cubic CdS and the hexagonal ZnO phase in the nanocomposites was described. The mechanism analysis suggested that sufficient grinding and heating treatment was a key to form the ZnO/CdS nanocomposites, and the surfactant PEG400 was proved not to involve the reaction and prevent the nanoparticles from aggregating to larger in whole grinding and heat-treatment process. Ultraviolet-visible (UV-vis) spectra revealed that the band gaps of the nanocomposites could be tuned by the reaction temperature and reaction time. Photoluminescence (PL) spectra showed that the changing position and the intensity of the emission peaks resulted from the rate of electron transfer and recombination probability under the different conditions. (C) 2014 Elsevier B.V. All rights reserved.
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