Journal
RADIATION PHYSICS AND CHEMISTRY
Volume 67, Issue 5, Pages 613-616Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0969-806X(03)00146-4
Keywords
hydrogen atom; hydrogen peroxide; chloride ion; chlorine; rate constant
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The rate constant for the reaction H-. + H2O2 --> (OH)-O-. + H2O was newly determined to be 3.5 x 10(7) dm(3) mol(-1) s(-1) by observing the Cl-2(.-) absorbance in pulse radiolysis experiments involving very pure acidic aqueous solutions of chloride ions and hydrogen peroxide. A reaction mechanism for the generation of Cl-2(.-) is described. (C) 2003 Elsevier Science Ltd. All rights reserved.
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