Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 6, Issue 7, Pages 852-854Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(03)00122-9
Keywords
crystal structure; synthesis; luminescence; antenna effect; praseodymium
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A new tetrakis praseodymium(tu) complex Pr(TFNB)(3)Phen has been synthesized, in which TFNB is 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione and Phen is 1,10-phenanthroline. Its crystal structure and luminescent spectra were successfully determined and investigated. The typical antenna effect existing in the luminescence of Pr(TFNB)(3)Phen was revealed by the study of the UV-Vis absorption spectra of ligands and the excitation spectrum of Pr(TFNB)(3)Phen. (C) 2003 Elsevier Science B.V. All rights reserved.
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