Facile fabrication of graphene/nickel oxide composite with superior supercapacitance performance by using alcohols-reduced graphene as substrate

Graphene/nickel oxide composite (G/NiO) was synthesized through a facile hydrothermal method and subsequently microwave thermal treatment by using alcohols-reduced graphene as substrate. The as-prepared G/NiO was characterized by X-ray diffraction, Raman spectra, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscope and transmission electron microscope. The results indicate that the graphene oxide has been successfully reduced to graphene, and NiO nanoparticles are homogeneous anchored on the surface of graphene, forming a globule-on-sheet structure. The loading content of NiO nanoparticles anchoring on the surface of graphene nanosheets can be controlled by adjusting the hydrothermal temperature. The G/NiO displays superior electrochemical performance with a specific capacitance of 530 F g(-1) at 1 A g(-1) in 2 M of NaOH. After 5000 cycles, the supercapacitor still maintains a specific capacitance of 490 F g(-1) (92% retention of the initial capacity), exhibiting excellent cycling stability. (C) 2015 Elsevier B.V. All rights reserved.