Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 13, Pages 2389-2392Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200300017
Keywords
cobalt; Schiff-base ligand; thiolate
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The dinuclear [(CoCoIII)-Co-III] complexes [Co-2(L-1)(mu-OAc)(OAc)-(NH3)](PF6)(2) and [(CO2(L-2)(2)(mu-OAc)](PF6), incorporating the rare Co(mu-SR)(2)Co moiety associated with Schiff-base co-ligands, are protected by bridging mu-OAc- units situated within a domed cavity formed by the complexes; increasing the steric bulk of the ligand, as in [L-3](2-), affords the mononuclear species [Co(L-3)(OAc)]. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
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