Journal
DALTON TRANSACTIONS
Volume -, Issue 13, Pages 2627-2635Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b303502f
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This article addresses fundamental. mechanistic aspects related to the perfectly alternating copolymerisation of CO and ethene in MeOH through the analysis of both actual reactions catalysed by palladium(II)-diphosphine precursors and stoichiometric reactions with model compounds. Most recent in situ studies of CO/ethene copolymerisation, applying high-pressure IR and NMR techniques, have been reviewed and commented.
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