Journal
TETRAHEDRON LETTERS
Volume 44, Issue 28, Pages 5335-5338Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(03)01200-0
Keywords
oxaziridines; amination; sulfimides
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The effect of solvent polarity on the reaction of 3-aryl-N-carboxamido- and 3-aryl-N-alkoxycarbonyl oxaziridines has been studied and an efficient procedure for high yielding sulfimidation developed by use of polar solvents. The first examples of asymmetric sulfimidation using novel chiral oxaziridines have been carried out with low diastereoselectivity (up to 30% de). (C) 2003 Elsevier Science Ltd. All rights reserved.
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