4.8 Article

Ion multivalence and like-charge polyelectrolyte attraction

Journal

PHYSICAL REVIEW LETTERS
Volume 91, Issue 2, Pages -

Publisher

AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.91.028301

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It is known empirically that multivalent ions generate attractions between like-charged polyelectrolytes, with different valence requirements for different systems. How multivalent must an ion be before it can condense a given polyelectrolyte? Using charge-tunable M13 virus rods and a family of artificial homologous dumbbell divalent ions of different sizes, we have constructed a multivalent ion-polyelectrolyte phase diagram, and find an experimentally motivated general criterion for like-charged attraction based on the ion valence, ion size, and the Gouy-Chapman length.

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