Journal
PHYSICAL REVIEW B
Volume 68, Issue 3, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.68.035416
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Electron tunneling through self-assembled monolayers (SAM's) of alkanethiols is investigated using nanometer-scale devices. Temperature-dependent current-voltage measurements are performed on alkanethiol SAM's to distinguish between different conduction mechanisms. Temperature-independent electron transport is observed, proving that tunneling is the dominant conduction mechanism of alkanethiols, as well as exhibiting an exponential dependence of tunneling current on the molecule length with a decay coefficient beta. From the bias dependence of beta, a barrier height Phi(B) of 1.39 +/- 0.01 eV and a zero-field decay coefficient beta(0) of 0.79 +/- 0.01 Angstrom(-1) are determined for alkanethiols.
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