Journal
TETRAHEDRON
Volume 59, Issue 30, Pages 5685-5689Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(03)00879-2
Keywords
arylation; aryl halides; palladium and compounds; thiazoles
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Thiazole, 2-phenyl or -alkyl substituted one and benzothiazole are efficiently arylated with aryl bromides at the 2- and/or 5-position(s) in the presence of Pd(OAc)(2) and a bulky phosphine ligand using Cs2Co3 as base. 2-Phenyl-5-thiazolecarboxanilide undergoes successive diarylation at the 4- and 5-positions accompanied by decarbamoylation. (C) 2003 Elsevier Ltd. All rights reserved.
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