Journal
ORGANIC LETTERS
Volume 5, Issue 15, Pages 2759-2761Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol035083d
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Novel synthetic methods of both ortho-alkenylated aromatic ketones and isoquinoline derivatives have been developed through the Rh(I)-catalyzed direct ortho-alkenylation of common aromatic ketimines with alkynes. Furthermore, a highly efficient one-pot synthesis of isoquinoline derivatives was achieved by simply mixing aromatic ketone, benzylamine, and alkyne under a Rh(I) catalyst.
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