Journal
MONATSHEFTE FUR CHEMIE
Volume 134, Issue 8, Pages 1081-1092Publisher
SPRINGER WIEN
DOI: 10.1007/s00706-003-0615-y
Keywords
acrylics; hydrolysis; kinetics; NMR spectroscopy; organofunctional silanes
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Various methacryloyloxymethylalkoxysilanes have been synthesized by nucleophilic substitution reactions starting from chloromethylalkoxysilanes under phase transfer catalysis conditions. The compounds thus obtained show an exceptionally high degree of reactivity with regard to hydrolysis and condensation both under acidic as well as under basic conditions compared to the established 3-methaeryloyloxypropyltrimethoxysilane. A mechanistic model for this high reactivity by intramolecular activation is discussed.
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