Long-term variations in dissolved trace elements in the Sagami River and its tributaries (upstream area), Japan

We investigated long-term variations in dissolved chemical species in water sampled from the Sagami River and its tributaries, Japan. The samples were taken monthly from May 1993 to April 2000 at 28 sampling sites in the Sagami River system. In this paper, we concentrate on 17 sites in the upper catchment. Twenty-four major to trace elements (Li, Mg, Al, Ca, V, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Me, Ag, Cd, Sb, Cs, Ba, W, Tl, Pb, U) were determined by using conventional Q-pole ICP-MS with direct nebulizalion. Water flux was measured from 1995. The data for most species were subjected to fast Fourier transformation (FFT) to extract dominant periodicities, their magnitudes, and their phases. Clear seasonal variations were observed for Al, V, As, Rb and Cs at some sampling points, especially in the tributaries. The seasonal variations may be due to either anthropogenic causes, such as irrigation or wastewater discharge, or natural causes, such as water temperature, pH, redox condition, water flux, or activity of microorganisms. We found no correlation with pH. Water temperature may not be a main controlling factor, although the seasonal variability would be correlated with it. Hydrologic factors may have only minor effects. We suggest that most of the seasonal variation might be correlated with the irrigation of rice paddies. It was difficult to identify all the causes of the seasonal variability. To investigate interannual trends, we used centered 12-month moving averages to eliminate seasonal variations. The water quality of the uppermost streams was generally constant, being controlled by springs on Mt. Fuji. However, in 1993 and 1998, V, As, Rb, Cs and U were depleted briefly, possibly by dilution by overflow from Lakes Kawaguchi and Yamanaka. Hydrologic factors may be more important for interannual variability than seasonal variability. Some heavy trace elements (Zn, Ni, Cd and Sb) showed very irregular variations with high concentration peaks. These elements were discharged from either factories or abandoned mine tailings. (C) 2003 Elsevier Science B.V. All rights reserved.