Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 119, Issue 5, Pages 2623-2637Publisher
AMER INST PHYSICS
DOI: 10.1063/1.1586912
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We present perturbational ab initio calculations of the leading-order one-electron relativistic contributions to the nuclear magnetic resonance shielding tensor based on the Pauli Hamiltonian. The scalar relativistic and spin-orbit interaction effects, including both relativistic corrections to the wave function (passive relativistic effects) and relativistic magnetic perturbation operators (active effects), are considered for H2X (X=O, S, Se, Te, Po), HX (X=F, Cl, Br, I, At), and noble gas (Ne, Ar, Kr, Xe, Rn) systems. The perturbational corrections are calculated using linear and quadratic response theory applied to nonrelativistic reference states. We use the uncorrelated self-consistent field as well as correlated, multiconfigurational complete active space self-consistent field models. Results for the H-1 and heavy-atom shielding constants and anisotropies are compared with Dirac-Hartree-Fock and quasirelativistic data. (C) 2003 American Institute of Physics.
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