Journal
JOURNAL OF PLANT NUTRITION AND SOIL SCIENCE
Volume 166, Issue 4, Pages 422-431Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jpln.200321152
Keywords
soil phosphorus; availability; P status, method; robust statistics
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Each European country is using its own method for the determination of phosphorus availability to plants, together with an appropriate interpretation scheme of the P status and fertilizer recommendations. In order to compare systems, a soil exchange program was organized: 16 P methods were compared on 135 soils from 12 countries. The amount of extracted P decreased in the order P-total > P-oxal. > P-AL > P-Me3 > P-Bray > P-AAEDTA, P-DL, P-CAL > P-Olsen > P-paper (strip), P-AAAc, P-Morgan > P-H2O, P-CO2, P-CaCl2, Isotopically exchangeable P was also measured. A large variability was observed in the results obtained by laboratories using the same method, thus demonstrating the great importance of an identical lab procedure as a prerequisite to any comparison. The traditional correlation/regression approach revealed its limitations when applied to non-homogeneously distributed data and was replaced by more robust techniques that showed laboratory differential bias and confidence intervals of the log-transformed values. Even though all the methods reacted in the same way to increasing amounts of added P in several trials, there were wide differences between results obtained with different methods. The interpretation schemes for P status were also compared and revealed that about 50% of the tested soils were P-deficient. This observation appears not to be in line with a generally high P fertilization during the last decades in Europe and should lead to a better evaluation of the plant-available soil phosphorus.
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