Journal
STRUCTURAL CHEMISTRY
Volume 14, Issue 4, Pages 417-419Publisher
KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1024410229577
Keywords
orbital degeneracy; triplet ground states; ethylenedione; carbenes; carbon allotropes; carbon-carbon quadruple bond
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Hypothesized accidental orbital degeneracies, from origins other than symmetry, in the second principal quantum level lead to surprising new chemistry of carbenes, aromatic compounds, and, most interestingly, to a possible new allotrope of carbon. Consequences of degeneracies in the transition metals are hinted at.
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