Journal
PURE AND APPLIED CHEMISTRY
Volume 75, Issue 8, Pages 1061-1068Publisher
INT UNION PURE APPLIED CHEMISTRY
DOI: 10.1351/pac200375081061
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Encapsulation of chromophores within Cram-type hemicarcerands allowed the investigation of fundamental photophysical phenomena, such as long-range triplet energy transfer, electron transfer, and the remote heavy atom effect. Furthermore, novel water-soluble hemicarcerands are being used to develop unique hybrid materials composed of semiconductor nanoparticles and host-guest assemblies. Photoinduced charge injection from the incarcerated guest into the conduction band of the semiconductor has been demonstrated.
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