Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 345, Issue 8, Pages 963-966Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200303057
Keywords
arenecarbaldehydes; arenes; arylamines; aza-Diels-Alder reaction; clays; methylenecyclopropanes; heterogeneous solid acid catalysts; montmorillonite KSF; quinolines
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A series of novel quinoline derivatives having a spirocyclopropyl ring can be synthesized by one-pot, three-component aza-Diels-Alder reactions of arenecarbaldehydes, arylamines, and methylenecyclopropanes (MCPs) using a heterogeneous solid acid catalyst, montmorillonite KSF, under mild reaction conditions in good to excellent yields.
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