Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 202, Issue 1-2, Pages 47-64Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-1169(03)00249-8
Keywords
amino acid supported Pd catalysts; hydrogenation; catalytic activity; reusable catalysts; high pressure kinetics
Categories
Ask authors/readers for more resources
L-Valine was anchored to 6% and 8% cross-linked poly(styrene-divinyl benzene) resin and its complex with palladium chloride was prepared. The newly synthesized catalysts were characterized by various techniques such as elemental analysis, FT-IR, DRS, SEM and TGA. Physico-chemical properties like surface area, swelling behavior in different solvents, bulk density, etc. have been determined. The polymer supported Pd complexes behave as versatile and recyclable catalysts for the hydrogenation of 1-octene, cyclohexene, acetophenone and nitrobenzene. Kinetics of hydrogenation of I-octene has been investigated in detail. The influence of different reaction parameters on conversion and selectivity to products are reported. (C) 2003 Elsevier Science B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available