Journal
SYNLETT
Volume -, Issue 10, Pages 1431-1434Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2003-40859
Keywords
allylations; arenes; catalysis; iridium; rhodium
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The allylation of electron-rich arenes with allyl tosylate roceeded at 0 degreesC in the presence of [Rh(nbd)(CH3CN)(2)]PF6. Various oxygenated arenes were allylated with high para-selectivity in almost all cases. Especially in the reaction of anisoles, the tendency was remarkable.
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