Journal
CHEMISTRY OF MATERIALS
Volume 15, Issue 16, Pages 3063-3073Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm031018m
Keywords
-
Ask authors/readers for more resources
A new supramolecular crystal engineering approach toward quadratic nonlinear optics is inferred from an acentric cocrystalline template made of two different bi-dimensional octupolar molecules: trinitrobenzene (TNB) and triphenylene (TP). The resulting 2-D octupolar cocrystalline lattice is proposed as a generic template toward multipolar crystalline engineering studies. X-ray diffraction data evidence parallel stacks with alternating vertically overlapping TNB and TP units, leading to a significant, pi-pi intermolecular charge transfer which cannot be accounted for by an oriented gas model.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available