Journal
ORGANIC LETTERS
Volume 5, Issue 17, Pages 3069-3072Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol035097j
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Funding
- NCRR NIH HHS [RR00954] Funding Source: Medline
- NIGMS NIH HHS [R01 GM56490] Funding Source: Medline
- PHS HHS [1S10R02004] Funding Source: Medline
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graphic Work toward the development of a bisphosphine ligand system for the palladium-catalyzed addition to cyclic allyl acetates is reported. A parallel approach using phosphine-containing amino acids in conjunction with natural amino acids was used to develop a selective ligand system. The ligand system was examined while attached to the polymer support as well as in solution. Selectivites with the difficult substrate 3-acetoxycyclopentene of up to 95% ee are reported.
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