Journal
JOURNAL OF HETEROCYCLIC CHEMISTRY
Volume 40, Issue 5, Pages 845-850Publisher
WILEY
DOI: 10.1002/jhet.5570400515
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We report the synthesis of various thiophene/phenylene co-oligomers with a total number of thiophene and benzene (phenylene) rings of 6 to 8. These compounds include a phenyl-capped sexithiophene, a thienyl-capped quaterphenylene, as well as block and alternating co-oligomers. The synthesis is based on either the Suzuki coupling reaction or the direct dimerization coupling. The latter method produces symmetric molecules with an even total ring number. These reaction schemes enabled us to obtain the target compounds in high quality. Although the resulting materials are difficult to dissolve in organic solvents and therefore difficult to identify by usual H-1 nmr spectroscopy, they have successfully been identified through Fourier-transform ir spectroscopy. The specific group frequencies of ring-stretching and out-of-plane deformation modes are characteristic of the substitution pattern of the individual thiophene and benzene rings.
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