Journal
CATALYSIS COMMUNICATIONS
Volume 4, Issue 9, Pages 455-459Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1566-7367(03)00112-2
Keywords
solid base catalyst; KF loaded on alumina; hydrosilylation; Peterson olefination; silyl-reformatsky reaction
Categories
Ask authors/readers for more resources
KF loaded on alumina heated under vacuum at 673 K (KF/Al2O3) quantitatively gave benzyloxytriethylsilane by addition of triethylsilane to benzaldehyde at 303 K in N,N-dimethylformamide (DMF). KF/Al2O3 also catalyzed the reaction of trimethylsilylacetonitrile with benzaldehyde to give 3-phenyl-3-(trimethylsilyloxy)propionitrile with a 81% yield at 313 K in tetrahydrofuran (THF) while it gave cinnamonitrile with a 61% yield in DMF, along with trimethylsilanol. (C) 2003 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
