Chemical brecciation processes in the Sue unconformity-type uranium deposits, Eastern Athabasca Basin (Canada)

Chemical brecciation in sandstone is common in many unconformity-type uranium deposits of the Athabasca Basin, and is expressed in some of them as ball zone breccia. Ball zones are composed of rounded argillized sandstone fragments, varying in size from several centimeters to 1 m, wrapped in a clay matrix. The Sue C open pit provided a unique opportunity to map and to study such ball zones. Here, they were up to 5 m wide with a 20-30 m vertical extension. They were mainly observed along a reverse fault controlling the Sue A and B uranium deposits, and were well developed at intersections with dextral NE-trending structures. Their maturity, characterized by the matrix percentage, increased toward the unconformity and at fault intersections. They are characterized by massive quartz dissolution, hematite leaching, (Ca,SrLREE)Al-phosphates crystallization and replacement of dickite by illite. Illite composition indicates formation temperatures of 240-280 degreesC, close to peak diagenesis conditions in the basin. Mass balance calculations show that V, K, Rb, B, LREE, Mg, Cr, Sr, U and Y were added and Si and Fe leached out with up to 85% volume loss. Ball zones were initiated by tectonic fracturing in sandstone during reverse faulting. Consecutive permeability increase induced basement fluid circulation in the sandstone with quartz dissolution along fractures. With a silica saturation of the fluid of 90%, a minimum fluid/rock ratio of 38,000 is obtained. The rounded morphologies of the breccia fragments are attributed to a diffusion-limited regime of dissolution. The resulting increase of clay content led to self-sealing of the hydrothermal system. Seismic reactivation may have been periodically rejuvenated the permeability. These processes seem to be coeval with the formation of structurally controlled high-grade unconformity-type uranium mineralization. Formation of the ball zones required probably more than 1 million years. (C) 2003 Elsevier B.V. All rights reserved.