Journal
SUPRAMOLECULAR CHEMISTRY
Volume 15, Issue 6, Pages 447-450Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/1061027031000147485
Keywords
porphyrin; self-organization; crystal structure; hydrogen bonding
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The cis-doubly N-confused porphyrin (cis-N2CP, 1) and its Cu(III) and Ag(III) complexes (1-Cu, 1-Ag) form 1-D zigzag infinite chains through hydrogen-bonding interactions between the peripheral core nitrogens (N and NH) in the solid state. Each columnar structure consists of porphyrin rings with the same chirality.
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