Journal
PHYSICAL REVIEW E
Volume 68, Issue 3, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.68.032501
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Nonequilibrium electro-osmotic slip causes instability of quiescent ionic conductance through a diffusion layer of a strong electrolyte at a charge selective solid such as ion-exchange membrane or electrode. This instability, as inferred from the outer asymptotic limit of the full singularly perturbed ionic transport problem, is of the short-wave type. This latter is a serious shortcoming of the limiting model. In this Brief Report we show that inclusion in the model of the first asymptotic corrections yields a reasonable finite wavelength selection.
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