Journal
PURE AND APPLIED CHEMISTRY
Volume 75, Issue 9, Pages 1305-1313Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200375091305
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New applications in which the carborane and metallacarborane species play a crucial role have been recently developed. In these applications, clusters display many particular characteristics that do not find parallel in their organic counterparts. The o-carborane can modulate the C...C distances depending on the substituents bonded to the cluster carbon atom and can lead to the formation of uncommon halogenophosphane charge-transfer spoke complexes with iodine due to their electron-withdrawing capacity. Besides, metallacarboranes have been used as doping agents in organic conducting polymers and as catalysts in Kharasch reactions.
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