Journal
ORGANIC LETTERS
Volume 5, Issue 18, Pages 3201-3203Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol034983r
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[GRAPHICS] A new ligand for Cu-catalyzed enantioselective additions of dialkylzincs to cyclic enones has been developed. In addition to providing good to excellent enantioselectivities with a range of cyclic enones and dialkylzincs, the ligand has several notworthy features: it can be readily prepared in just two steps, is an air-stable crystalline solid, and provides optimal performance at ambient temperature.
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