Journal
ORGANIC LETTERS
Volume 5, Issue 18, Pages 3225-3228Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol035053a
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[GRAPHICS] Palladium complexes (1 and 2) were immobilized in ionic liquids, and their applications to catalytic asymmetric fluorination and Michael reaction of beta-ketoesters were successfully demonstrated. This immobilization enabled the reuse of the catalysts no less than 10 times in fluorination and 5 times in Michael reaction with levels of efficiency comparable to those obtained in usual organic solvents.
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