4.4 Article

Radical-mediated hydroxytrifluoromethylation of α,β-unsaturated esters

Journal

TETRAHEDRON LETTERS
Volume 44, Issue 37, Pages 7027-7029

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(03)01783-0

Keywords

hydroxytrifluoromethylation; alpha,beta-unsaturated esters; radical reaction

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Treatment of alpha,beta-unsaturated esters with trifluoromethyl iodide and triethylborane in the presence of KF and H2O gave the corresponding hydroxytrifluoromethylated esters. (C) 2003 Elsevier Ltd. All rights reserved.

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