Journal
ORGANIC LETTERS
Volume 5, Issue 19, Pages 3399-3402Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0300773
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Pretreatment of a symmetrical primary or secondary diamine with 9-BBN prior to the addition of an acyl chloride significantly suppressed undesired diacylation, and the product of monoacylation predominated. The reactive preference is interpreted as the result of a selective deactivation of one nitrogen atom of the diamine by 9-BBN.
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